N,N′,N′′-Tris(2-nitrobenzyl)-2,2′,2′′-nitrilotriethanaminium trichloride 1.41-hydrate
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چکیده
منابع مشابه
N,N′,N′′-Tris(2-nitrobenzyl)-2,2′,2′′-nitrilotriethanaminium trichloride 1.41-hydrate
The title compound, C(27)H(36)N(7)O(6) (3+)·3Cl(-)1.41H(2)O, is the hydro-chloride of a tripodal amine, and was structurally characterized because the free base, used as a ligand in podate complexes, is an oily material. In the cation, the secondary amine groups are protonated, and, despite the induced Coulombic repulsions, a claw-like conformation is stabilized, with a cavity approximating C(3...
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The asymmetric unit of the title compound, C18H15N6 (3+)·3Cl(-)·2.5H2O, contains two independent (1,3,5-triazine-2,4,6-tri-yl)tripyridinium cations. Both cations are approximately planar, the r.m.s. deviations of fitted non-H atoms being 0.045 and 0.051 Å. In the crystal, extensive O-H⋯Cl, O-H⋯O, N-H⋯Cl and N-H⋯O hydrogen bonds and weak C-H⋯Cl and C-H⋯O inter-actions link the organic cations, C...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809022399